Fixing Outlook 2010 Stay-On-Top Problem
From ATTWiki
Close Outlook.
In the Search Programs and Files box, enter RegEdit and press Enter.
Search for this folder: HKey_Current_User\Software\Microsoft\Office\Outlook\Addins.
Each add-in can use a DWORD called LoadBehavior.
If the value is set to 3 instead of 2, this will cause Outlook’s main window to be at the top of the Z stack when the window is open, preventing any other window opening in front of it.
Create the key LoadBehavior and set it to 2.
Load Outlook.
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